Rate
Law: In
rate law, the concentrations of reactants are raised to some power which may or
may not be equal to the Stoichiometric coefficient of the reaction.
Law of Mass Action: In the law of mass
action, the concentrations of reactants and products are raised to the power of
their Stoichiometric coefficient.
The main difference between rate law and law of mass action is
that, rate law is given considering only the reactants of a reaction whereas
law of mass action is given considering both reactants and products of a
reaction.
The
Rate Law cannot be determined by just looking at the given chemical equation
but, instead, can be determined only experimentally. However, the Law of Mass
Action can be determined by just looking at the chemical equation.
According
to this “Law of Mass Action”, for a given reaction of the form:
aA + bB —→ Products,
the rate of reaction = k[A]^a[B]^b
where k is the equilibrium constant.
aA + bB —→ Products,
the rate of reaction = k[A]^a[B]^b
where k is the equilibrium constant.
But experimentally, it has been found out that the rate of
reaction may not necessarily depend on all the ‘a’ concentration terms of A or
on all the ‘b’ concentration terms of B but only on some partial amount of the
total concentration of A or B, say, x and y respectively.
i.e.,
Rate of Reaction = k[A]^x[B]^y
where, x and y may or may not be equal to a and b.
This above expression is called Rate Law.
i.e.,
Rate of Reaction = k[A]^x[B]^y
where, x and y may or may not be equal to a and b.
This above expression is called Rate Law.
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