Wednesday 30 January 2019

all acids strength strong acid to weak acid


Table of Acid and Base Strength


Ka
Acid
Base
Name
Formula
Formula
Name
Large
Perchloric acid
HClO4
ClO-
Perchlorate ion
3.2 * 109
Hydroiodic acid
HI
I-
Iodide
1.0 * 109
Hydrobromic acid
HBr
Br-
Bromide
1.3 * 106
Hydrochloric acid
HCl
Cl-
Chloride
1.0 * 103
Sulfuric acid
H2SO4
HSO4 -
Hydrogen sulfate ion
2.4 * 101
Nitric acid
HNO3
NO3 -
Nitrate ion
--------
Hydronium ion
H3O+
H2O
Water
5.4 * 10-2
Oxalic acid
HO2C2O2H
HO2C2O2-
Hydrogen oxalate ion
1.3 * 10-2
Sulfurous acid
H2SO3
HSO3 -
Hydrogen sulfite ion
1.0 * 10-2
Hydrogen sulfate ion
HSO4 -
SO4 2-
Sulfate ion
7.1 * 10-3
Phosphoric acid
H3PO4
H2PO4 -
Dihydrogenphosphate ion
7.2 * 10-4
Nitrous acid
HNO2
NO-
Nitrite ion
6.6 * 10-4
Hydrofluoric acid
HF
F -
Fluoride ion
1.8 * 10-4
Methanoic acid
HCO2H
HCO2 -
Methanoate ion
6.3 * 10-5
Benzoic acid
C6H5COOH
C6H5COO-
Benzoate ion
5.4 * 10-5
Hydrogen oxalate ion
HO2C2O2-
O2C2O2 2-
Oxalate ion
1.8 * 10-5
Ethanoic acid
CH3COOH
CH3COO
Ethanoate (acetate) ion
4.4 * 10-7
Carbonic acid
CO3 2-
HCO3 -
Hydrogen carbonate ion
1.1 * 10-7
Hydrosulfuric acid
H2S
HS-
Hydrogen sulfide ion
6.3 * 10-8
Dihydrogen phosphate ion
H2PO4 -
HPO4 2-
Hydrogen phosphate ion
6.2 * 10-8
Hydrogen sulfite ion
HS-
S2-
Sulfite ion
2.9 * 10-8
Hypochlorous acid
HClO
ClO-
Hypochlorite ion
6.2 * 10-10
Hydrocyanic acid
HCN
CN-
Cyanide ion
5.8 * 10-10
Ammonium ion
NH4 +
NH3
Ammonia
5.8 * 10-10
Boric acid
H3BO3
H2BO3 -
Dihydrogencarbonate ion
4.7 * 10-11
Hydrogen carbonate ion
HCO3 -
CO3 2-
Carbonate ion
4.2 * 10-13
Hydrogen phosphate ion
HPO4 2-
PO4 3-
Phosphate ion
1.8 * 10-13
Dihydrogen borate ion
H2BO3-
HBO3 2-
Hydrogen borate ion
1.3 * 10-13
Hydrogen sulfide ion
HS-
2-
Sulfide ion
1.6 * 10-14
Hydrogen borate ion
HBO3 2-
BO3 3-
Borate ion
---------
water
H2O
OH-
Hydroxide


1. Strong acids are listed at the top left hand corner of the table and have Ka values >1
2. Acid with values less than one are considered weak.
3. The strong bases are listed at the bottom right of the table and get weaker as we move to the top of the table.

Tuesday 29 January 2019

jee organic all named reactions

class 12 organic named reactions

ioc solubility chart




Selected Solubility Products and Formation Constants at 25oC
Solubility Rules

Although all compounds have a characteristic solubility in water at a given temperature, some families of compounds are more soluble than others and it is useful to know certain general rules of solubility. We call any substance the solubility of which is less than 0.01 mol/L insoluble. If its solubility is greater than 0.1 mol/L, we call it soluble. If its solubility is between 0.01 and 0.1 mol/L, we say that it is slightly soluble. The following solubility rules can be used to determine solubilities in water, with the disclaimer that they don't always hold, nor do they include every ion which is in common use, but they are good to have nearby when needed:

1. All sodium, potassium, and ammonium salts are soluble.
2. All nitrates, acetates and perchlorates are soluble.
3. All silver, lead and mercury(I) salts are insoluble.
4. All chlorides, bromides and iodides are soluble.
5. All carbonates, sulfides, oxides and hydroxides are insoluble.
6. All sulfates are soluble except strontium sulfate and barium sulfate.

That having been said, here is a table of solubility product constants. 
CompoundFormulaKsp
aluminum hydroxideAl(OH)34.6 x 10-33
aluminum phosphateAlPO46.3 x 10-19
barium carbonateBaCO35.1 x 10-9
barium chromateBaCrO42.2 x 10-10
barium fluorideBaF21.0 x 10-6
barium hydroxideBa(OH)25 x 10-3
barium iodateBa(IO3)21.5 x 10-9
barium oxalateBaC2O42.3 x 10-8
barium sulfateBaSO41.1 x 10-10
barium sulfiteBaSO38 x 10-7
barium thiosulfateBaS2O31.6 10-5
bismuthyl chlorideBiOCl1.8 x 10-31
bismuthyl hydroxideBiOOH4 x 10-10
bismuth(III) sulfideBi2S31 x 10-97
cadmium carbonateCdCO35.2 x 10-12
cadmium hydroxideCd(OH)22.5 x 10-14
cadmium iodateCd(IO3)22.3 x 10-8
cadmium sulfideCdS8.0 x 10-27
calcium carbonateCaCO33.8 x 10-9
calcium chromateCaCrO47.1 x 10-4
calcium fluorideCaF25.3 x 10-9
calcium hydroxideCa(OH)25.5 x 10-6
calcium iodateCa(IO3)27.1 x 10-7
calcium oxalate hydrateCaC2O4.H2O1.96 x 10-8
calcium hydrogen phosphateCaHPO41 x 10-7
calcium phosphateCa3(PO4)21 x 10-26
calcium sulfateCaSO49.1 x 10-6
calcium sulfiteCaSO36.8 x 10-8
chromium(II) hydroxideCr(OH)22 x 10-16
chromium(III) hydroxideCr(OH)36.3 x 10-31
cobalt(II) carbonateCoCO31.4 x 10-13
cobalt(III) hydroxideCo(OH)31.6 x 10-44
cobalt(II) sulfideCoS4.0 x 10-21
copper(I) chlorideCuCl1.2 x 10-6
copper(I) cyanideCuCN3.2 x 10-20
copper(I) iodideCuI1.1 x 10-12
copper(I) sulfideCu2S2.5 x 10-48
copper(II) arsenateCu3(AsO4)27.6 x 10-36
copper(II) carbonateCuCO31.4 x 10-10
copper(II) chromateCuCrO43.6 x 10-6
copper(II) ferrocyanideCu2[Fe(CN)6]1.3 x 10-16
copper(II) hydroxideCu(OH)22.2 x 10-20
copper(II) sulfideCuS6 x 10-37
copper(II) thiocyanateCu(SCN)24.0 x 10-14
fluorapatiteCa5(PO4)3F1.0 x 10-60
hydroxyapatiteCa5(PO4)3OH1.0 x 10-36
iron(II) carbonateFeCO33.2 x 10-11
iron(II) hydroxideFe(OH)28.0 x 10-16
iron(II) sulfideFeS6 x 10-19
iron(III) arsenateFeAsO45.7 x 10-21
iron(III) ferrocyanideFe4[Fe(CN)6]33.3 x 10-41
iron(III) hydroxideFe(OH)34 x 10-38
iron(III) phosphateFePO41.3 x 10-22
lead(II) arsenatePb3(AsO4)24.0 x 10-36
lead(II) azidePb(N3)22.5 x 10-9
lead(II) bromatePb(BrO3)27.9 x 10-6
lead(II) bromidePbBr24.0 x 10-5
lead(II) carbonatePbCO37.4 x 10-14
lead(II) chloridePbCl21.6 x 10-5
lead(II) chromatePbCrO42.8 x 10-13
lead(II) fluoridePbF22.7 x 10-8
lead(II) hydroxidePb(OH)21.2 x 10-5
lead(II) iodatePb(IO3)22.6 x 10-13
lead(II) iodidePbI27.1 x 10-9
lead(II) sulfatePbSO41.6 x 10-8
lead(II) sulfidePbS3 x 10-29
lithium carbonateLi2CO32.5 x 10-2
lithium fluorideLiF3.8 x 10-3
lithium phosphateLi3PO43.2 x 10-9
magnesium ammonium phosphateMgNH4PO42.5 x 10-13
magnesium arsenateMg3(AsO4)22.1 x 10-20
magnesium carbonateMgCO33.5 x 10-8
magnesium fluorideMgF23.7 x 10-8
magnesium hydroxideMg(OH)21.8 x 10-11
magnesium oxalateMgC2O47 x 10-7
magnesium phosphateMg3(PO4)21 x 10-25
manganese(II) carbonateMnCO31.8 x 10-11
manganese(II) hydroxideMn(OH)21.9 x 10-9
manganese(II) sulfideMnS2.5 x 10-13
mercury(I) bromideHg2Br25.6 x 10-23
mercury(I) chlorideHg2Cl25.0 x 10-13
mercury(I) chromateHg2CrO42.0 x 10-9
mercury(I) cyanideHg2(CN)25 x 10-40
mercury(I) iodideHgI24.5 x 10-29
mercury(I) sulfateHg2SO47.4 x 10-7
mercury(I) sulfideHg2S1.0 x 10-47
mercury(I) thiocyanateHg2(SCN)23.0 x 10-20
mercury(II) sulfideHgS1.6 x 10-52
mercury(II) thiocyanateHg(SCN)22.8 x 10-20
nickel(II) carbonateNiCO36.6 x 10-9
nickel(II) hydroxideNi(OH)22.0 x 10-15
nickel(II) sulfideNiS3 x 10-19
scandium fluorideScF34.2 x 10-18
scandium hydroxideSc(OH)34.2 x 10-18
silver arsenateAg3AsO41.0 x 10-22
silver acetateAgC2H3O22.0 x 10-3
silver azideAgN32.0 x 10-8
silver benzoateAgC7H5O22.5 x 10-5
silver bromateAgBrO35.5 x 10-5
silver bromideAgBr5.3 x 10-13
silver carbonateAg2CO38.1 x 10-12
silver chlorideAgCl1.8 x 10-10
silver chromateAg2CrO41.1 x 10-12
silver cyanideAgCN1.2 x 10-16
silver iodateAgIO33.0 x 10-8
silver iodideAgI8.3 x 10-17
silver nitriteAgNO26.0 x 10-4
silver oxalateAg2C2O43.6 x 10-11
silver sulfateAg2SO41.4 x 10-5
silver sulfideAg2S6 x 10-51
silver sulfiteAgSO31.5 x 10-14
silver thiocyanateAgSCN1.0 x 10-12
strontium carbonateSrCO31.1 x 10-10
strontium chromateSrCrO42.2 x 10-5
strontium fluorideSrF22.5 x 10-9
strontium oxalateSrC2O44 x 10-7
strontium sulfateSrSO43.2 x 10-7
strontium sulfiteSrSO34 x 10-8
thallium(I) bromateTlBrO31.7 x 10-4
thallium(I) bromideTlBr3.4 x 10-6
thallium(I) chlorideTlCl1.7 x 10-4
thallium(I) chromateTl2CrO49.8 x 10-15
thallium(I) iodateTlIO33.1 x 10-6
thallium(I) iodideTlI6.5 x 10-8
thallium(I) sulfideTl2S6 x 10-22
thallium(I) thiocyanteTlSCN1.6 x 10-4
thallium(III) hydroxideTl(OH)36.3 x 10-46
tin(II) hydroxideSn(OH)21.4 x 10-28
tin(II) sulfideSnS1 x 10-26
zinc carbonateZnCO31.4 x 10-11
zinc cyanideZn(CN)23 x 10-16
zinc hydroxideZn(OH)21.2 x 10-17
zinc iodateZn(IO3)23.9 x 10-6
zinc oxalateZnC2O42.7 x 10-8
zinc phosphateZn3(PO4)29.0 x 10-33
zinc sulfideZnS2 x 10-25
Formation Constants of Selected Complex Ions, at 25oCFormulaKf
Ag(CN)2-5.6 x 1018
Ag(NH3)2+1.7 x 107
Ag(S2O3)23-2.9 x 1013
Co(SCN)+100
Cu(CN)2-1.0 x 1016
Cu(NH3)42+1.0 x 1013
Fe(SCN)2+900
HgI42-4.2 x 1027
Zn(NH3)42+2.9 x 109
Zn(OH)42-4.6 x 1017

Wednesday 16 January 2019

Why is NH3 not written as H3N?



In inorganic chemistry and especially in binary compounds they have the habit to use an order based on electronegativity: the least electronegative element being cited first.
  • Sulfur hexafluoride: SF
  • Ammonia: NH
  • Calomel: HgCl
  • Diborane: BH
As correctly commented by Eric Ressner Ammonia does not follow the simple electronegativity rule: electronegativity of nitrogen is 3.0 hydrogen is 2.2 (Linus Pauling scale).
So I double checked the guidance: the correct element sequence is ‘inspired by’ electronegativity, but with a few exceptions. This is detailed in Table VI (p 260 of the red book):
By convention, the later an element occurs when the table is traversed following the arrows, the more electropositive is the element.
Hydrogen is placed on top of Nitrogen. So NH is following the ‘rule’.


ANCIENT SCIENCE

  https://www.youtube.com/watch?v=1eetRjqkUkQ&list=PLuR244LTfD1Dlu2JBzy6yKTCU1DBJv6oy&index=5 https://youtu.be/1eetRjqkUkQ